The above list is a
general list of mixing
classifications. There are more classifications that can be
added. The intent is to present a generalized discussion for an
understanding of mixing applications. Obviously, each specific application
presents its own set of complexities, which goes beyond our intent, which is the
assistance of helping to generally describe and understand a mixing application.
Blending of
Miscible Liquids:
Miscible generically means that two or more fluids that will mix together
readily and will not separate once mixed. Oil and water are immiscible,
where they will separate in and unmixed state. Almost all of these
applications are flow controlled applications. Fluids can be miscible and
can still separate, such as adding a small amount water to a large batch
that has a large viscosity difference, say 5,000 centipoise for example.
Dissolving:
Almost all dissolving operations are flow controlled applications. The
solubility of a solid is the maximum percent by weight solids that will dissolve
into a solution. If more solid is added, the solution becomes
supersaturated and is then classified a slurry. The solubility in water is
known for most substances. The solubility is dependent upon the
temperature, solvent, and the interaction with other
chemicals.
Heat Transfer:
Although heat transfer applications can be quite complex, most of these mixing
operations are flow controlled applications understanding some very basic
principles.
-
The energy imparted
by the mixers motor to the batch must be accounted for as a factor of heat
added to the system.
-
Heat transfer is
highly dependent upon the heat transfer area and the driving force
temperature differential, understanding that the heat transfer area is the
primary controlling factor.
-
In order to double
the heat transfer coefficient, the mixers horsepower would have to increase
by a factor of 11 times or more, understanding that it is impractical to
design a mixer to achieve a specific heat transfer coefficient.
-
Flow must be directed
across the heat transfer surface area.
Solid Suspension:
Free settling solids that are either insoluble or partially soluble are
generally classified under Solid Suspension. Most of these
applications are generally classified as flow controlled. Parameters such as
the density of the solvent, solid size distribution, percent by weight
solids, and the specific gravity of the solids (not bulk density), and the
degree of suspension (on-bottom, off-bottom, mid-depth, or uniform
suspension) are required design parameter in the design of a mixer.
High percent by weight solid applications are classified as hindered
settling and act closer to blending and slurry applications.
Chemical
Reaction:
Chemical Reactors can be quite complex, especially as viewed from the
micro-molecular scale. Generally speaking most are considered flow
controlled applications as they most often include general chemicals
blending. A polymerizer, for example, could be considered as a chemical
reactor but it is typically considered under a subcategory of high viscosity
applications. An very definite exothermic chemical reaction results from
the manufacture of Magnesium Hydroxide from Magnesium Oxide, but again this
application could be considered under the sub-categories of slurries or minerals
processing rather than chemical reactions.
Blending
of Immiscible Liquids:
A good example of two immiscible liquids would be oil & water such as seen
in a common salad dressing. Many of these types of immiscible liquid
applications are flow controlled as the general objective is to contact two or
more fluids to extract or strip a beneficial component from one of fluids,
followed by a simple phase separation. Where the process becomes complex,
for example, is in consideration of a design bubble size distribution for
diffusion in counter-current mixing columns.
Gas-Liquid
Dispersion:
The study and requirements of a particular Gas-Liquid applications can be quite
complex, involving a control vessel (temperature and pressure). At
relatively low gas-liquid concentrations, the process is considered flow
controlled. Most gas-liquid dispersions are consider flow controlled
dispersions. Pharmaceutical applications such as Fermentation, for example,
require relatively high (gas-liquid concentrations) superficial gas velocities,
where the mixer design combine both flow and fluid shear. The fluid shear
is necessary to create the required bubble size distribution for diffusion where
the flow ensure that the bubble entrains throughout the vessel. The
smaller the bubble size, the greater the overall surface area to enhance
diffusion. If the sheared bubbles coalesce (to grow together) uncontrolled
and do not entrain in an overall beneficial flow pattern, the efficiencies of
the system will suffer. If an adequate amount of torque (horsepower
divided by speed) is not adequate, the result will be either not enough fluid
shear or not enough flow to entrain the bubble flow distribution, which in
either case efficiencies will suffer.
Slurry
Mixing:
A slurry is created when solids partially dissolves in a particular
solvent. The most common solvent is water. The extent to which a
solid dissolves in a particular solvent is generally expressed in terms of its
solubility. Some solids, such as lime in water for example, is only
slightly or partially soluble, where the bulk of the solid does not dissolve in
water. What makes slurry mixing interesting, is that as the solid
dissolves in a particular solvent, or combinations of solvents, the
characteristics such as the viscosity of the slurry can change either slightly
or significantly. For some slurries, significant changes to the
viscosity may occur even at very low percent by weight solids
concentrations. For other applications, it is possible to have a
relatively low viscosity at weight percent by solids approaching 80% or
more. Others slurries are time dependent, such as thixotropic slurries,
where you could stand on a slurry left unmixed for weeks, where that same
slurry, once sheared could be a thin as water. The good news is that many
liquid-solid applications generally are known, where it's not necessary to
reinvent the wheel from a mixer viewpoint. On the other hand, pilot plant
studies may be required for unknown combinations of solids and
solvents.
Crystallization:
Crystallization involves two key steps, the formation of solid particles from
liquid solution (normally referred to as nucleation), and growth due to the
deposition of additional substances on existing particles. The driving
force behind both steps is the difference in chemical potential between the
solution (liquid phase) and the crystal (solid phase). Although the target
impurity content is directly attributable to both the phase equilibrium and
crystallization kinetics, crystallization is
considered more of an art than a science. The prime interrelated phenomena
at play is mixing fluid shear.
Dispersion
& Homogenation:
The intent of dispersion or homogenization is to obtain a particle size
reduction generally into a range of 5-25 microns. The process result of a
dispersing or homogenation type mixer design is directly dependent upon how the
energy or the horsepower is split and transformed between both fluid shear and
flow. If the bulk of the energy is transformed into shear and some
flow. This device is generally a very poor flow design, where the shear
intensity is focused into a zonal region, which could result in a hot spot
within the tank (horsepower transformed into heat energy). Both dispersion
and homogenization are tip speed dependent, where tip speed = (p*RPM*Impeller
Diameter), usually expressed in feet per second. There are two primary
methods of imparting shear. The first is to use a disperser or homogenizer
type mixer that splits the available horsepower into shear and flow. The
second, is to use a lower cost flow controlled mixer design in combination with
a separate high shear device such as a shearing mill. The intent would
then be to circulate the fluid/slurry into the high intensity shear zone of the
shearing mill.
Extraction
or Leeching:
The most common Leeching operation that we are all familiar with is in the
making of coffee. The solid (coffee) is contacted with a solvent water, to
remove a desirable component from the coffee solid. The same process is
applied to other raw materials like mining ore (gold, copper, platinum, etc.),
where the solvent removes the precious metal from the ore, and is later
processed to precipitate and recover the precious metal from the solvent.
Extraction is somewhat similar in that two immiscible phases are contacted or
mixed with each other, where a desirable material that is
in one phase diffuses to another phase upon contact. Bulb size
distribution for efficient mass transfer is a key requirement.
High
Viscosity Blending:
Generally speaking fluids with a resulting viscosity above 10,000 centipoise
would be considered beyond just a general blending application. Since
viscosity is a function of temperature, shear and time, applying a mixer design
to a high viscosity application can be quite involved. There are numerous
designs used for high viscosity applications that include props, high solidity
hydrofoils, pitch blade turbines, anchors, helical, double helical impeller and
other designs. The most common problem identified with high viscosity
applications is due to the formation of an ellipsoid around an impeller, where
the generated flow or mixing within the ellipsoid is vigorous. Heat
generation within this region can also be problematic, as there is no motion to
transfer the heat to the tank wall or coils. Outside the ellipsoid, the
blend time becomes infinite, or in other words, no mixing occurs in that
region. In short, homogenity can never be reached due to a misapplied
mixer to the application. Obviously, there are various other issues to
contend with dependent upon the applications requirements.
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